Dichlorido{N,N,N′-trimethyl-N′-(1H-pyrazol-1-yl-κN 2)methyl]ethane-1,2-diamine-κ2 N,N′}copper(II) methanol monosolvate
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Bromidobis[3-(1H-pyrazol-1-yl-κN 2)propionamide-κO]copper(II) bromide methanol monosolvate
The title copper(II) N-pyrazolylpropanamide (PPA) complex, [CuBr(PPA)(2)]Br, was obtained in 78% yield by treatment of CuBr(2) with an excess of the ligand in methanol. Crystallization from the mother liquid afforded the title compound, i.e. the methanol solvate [CuBr(C(6)H(9)N(3)O)(2)]Br·CH(3)OH or [CuBr(PPA)(2)]Br·MeOH, as bright green crystals. In the solid state, the title salt comprises is...
متن کاملAqua[1-(1,10-phenanthrolin-2-yl-κ2 N,N′)-1H-pyrazol-3-amine-κN 2](sulfato-κO)copper(II) methanol monosolvate dihydrate
In the title compound, [Cu(SO(4))(C(15)H(11)N(5))(H(2)O)]·CH(3)OH·2H(2)O, the Cu(II) ion is in a distorted square-pyramidal geometry, in which three N atoms from the chelating 1-(1,10-phenanthrolin-2-yl)-1H-pyrazol-3-amine ligand and one O atom from a sulfate anion define the basal plane and the O atom from the coordinating water mol-ecule is located at the apex. In the crystal, hydrogen-bondin...
متن کاملBis[tris(1H-pyrazol-1-yl-κN 2)methane]nickel(II) bis{[tris(1H-pyrazol-1-yl-κN 2)methane]tris(thiocyanato-κN)nickelate(II)} methanol disolvate
Attempts to prepare the mononuclear [(tpm)Ni(II)L(3)](-1) [tpm = tris-(1H-pyrazol-1-yl)methane and L = thio-cyanate] anion yielded the methanol-solvated salt, [(tpm)(2)Ni(II)][(tpm)Ni(II)(NCS)(3)](2)·2CH(3)OH or [Ni(C(10)H(10)N(6))(2)][Ni(NCS)(3)(C(10)H(10)N(6))](2)·2CH(3)OH. The asymmetric unit consists of half a centrosymmetric bis-[tris-(1H-pyrazol-1-yl)methane]-nickel(II) cation and an octa...
متن کامل[2,9-Bis(3,5-dimethyl-1H-pyrazol-1-yl-κN 2)-1,10-phenanthroline-κ2 N,N′]bis(thiocyanato-κN)cadmium(II)
In the title complex, [Cd(NCS)(2)(C(22)H(20)N(6))], the Cd(II) ion is in a CdN(6) coordination geometry which is inter-mediate between octa-hedral and trigonal-prismatic. The dihedral angles formed between the mean planes of the pyrazole rings and the phenanthroline system are 15.74 (15) and 16.30 (13)°. In the crystal, there is a π-π stacking inter-action involving two symmetry-related pyrazol...
متن کامل[2-(3,5-Dimethyl-1H-pyrazol-1-yl-κN 2)-1,10-phenanthroline-κ2 N,N′]bis(thiocyanato-κN)cadmium(II)
In the title complex, [Cd(NCS)(2)(C(17)H(14)N(4))], the Cd(II) ion is in a distorted trigonal-bipyramidal CdN(5) coordination geometry. In the crystal structure, there is a π-π stacking inter-action involving a pyrazole ring and a symmetry-related pyridine ring with a centroid-centroid distance of 3.578 (3) Å.
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ژورنال
عنوان ژورنال: IUCrData
سال: 2019
ISSN: 2414-3146
DOI: 10.1107/s2414314619006928